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61.
To determine the existence of p-nitrophenol (PNP)-lowering bacteria in intestine of Japanese coastal fish, the gastro-intestinal contents were incubated in Brain Heart Infusion (BHI) broth and minimal medium (MM) broths containing 1 mmol/L PNP at 30 °C for 7 days. Among 26 samples of 19 fish species, 17 samples showed a decrease in PNP of 0.5-0.8 mmol/L in BHI broth, but no decrease was shown in MM broth. Eighteen PNP-lowering bacterial strains were isolated from four fishes. All of the strains were identified as Lactococcus lactis subsp. lactis. Three L. lactis strains JS1-3 isolated from Japanese seabass Lateolabrax japonicus showed the highest PNP-lowering activity (0.44 mmol/L). Optimum temperature and pH for the growth and PNP decreasing corresponded with the marine environment. These results suggested that marine fishes have PNP decreasing bacteria in their intestine. These bacteria might protect host fish from toxicities of PNP and PNP related compounds. 相似文献
62.
Malarvannan G Takahashi S Isobe T Kunisue T Sudaryanto A Miyagi T Nakamura M Yasumura S Tanabe S 《Marine pollution bulletin》2011,63(5-12):172-178
Three species of sea turtles (green, hawksbill and loggerhead turtles) stranded along the coasts or caught (by-catch) around Ishigaki Island and Kochi, Japan were collected between 1998 and 2006 and analyzed for six organohalogen compounds viz., PBDEs, PCBs, DDTs, CHLs, HCHs and HCB. The present study is the first and foremost to report the occurrence of organohalogen compounds in the sea turtles from Japan. Among the compounds analyzed, concentrations of PCBs, DDTs and CHLs were the highest in all the turtle samples. PBDEs were ubiquitously present in all the turtle species. Comparing with the other two species, concentrations of organohalogens in green turtle were relatively low and decreasing trend in the concentrations were noted with increasing carapace length. Concentrations of OCs in sea turtles from the coasts of Ishigaki Island and Kochi were relatively low as compared to those from other locations in the world. 相似文献
63.
José H.A. Sobral Vivian M. de Castilho M.A. Abdu Hisao Takahashi I. Paulino Ulisses A.C. Gasparelo Daniela C.S. Arruda Matheus Mascarenhas C.J. Zamlutti C.M. Denardini Daiki Koga A.F. de Medeiros R.A. Buriti 《Journal of Atmospheric and Solar》2011,73(11-12):1520-1528
In an effort to better understand the dynamics of westward velocities of the nocturnal F-region plasma, the climatology of the westward traveling plasma bubbles – WTB – occurring during quiettime is studied here. The climatology of the WTB is analyzed here based on airglow images obtained during 14 quiet days between 2001 and 2006 at the Brazilian station São João do Cariri (Geographic 7.45°S, 36.5°W, dip ~20°S). The frequency of occurrence of the WTB maximizes in the descending phase of the solar cycle. The WTB velocities ranged between ~20 and 40 ms?1. The frequency of occurrence had a peak value of only 3.65% at 2345 LT. The maximum occurrence of the WTB was in July–September. No WTB have been observed from November until April in all years 2001–2006. We show for the first time theoretically that the WTB dominant forcing mechanisms during geomagnetically quiet days are westward thermospheric winds. 相似文献
64.
Molecular-scale mechanisms of distribution and isotopic fractionation of molybdenum between seawater and ferromanganese oxides 总被引:1,自引:0,他引:1
Teruhiko Kashiwabara Yoshio Takahashi Akira Usui 《Geochimica et cosmochimica acta》2011,75(19):5762-5784
The distribution of Mo between seawater and marine ferromanganese oxides has great impacts on concentration and isotopic composition of Mo in modern oxic seawater. To reveal the adsorption chemistry of Mo to ferromanganese oxides, we performed (i) detailed structural analyses of Mo surface complexes on δ-MnO2, ferrihydrite, and hydrogenetic ferromanganese oxides by L3- and K-edge XAFS, and (ii) adsorption experiments of Mo to δ-MnO2 and ferrihydrite over a wide range of pHs, ionic strengths, and Mo concentrations. XAFS analyses revealed that Mo forms distorted octahedral (Oh) inner-sphere complexes on δ-MnO2 whereas it forms a tetrahedral (Td) outer-sphere complex on ferrihydrite. In the hydrogenetic ferromanganese oxides, the dominant host phase of Mo was revealed to be δ-MnO2. These structural information are consistent with the macroscopic behaviors of Mo in adsorption experiments, and Mo concentration in modern oxic seawater can be explained by the equilibrium adsorption reaction on δ-MnO2. In addition, the large isotopic fractionation of Mo between seawater and ferromanganese oxides detected in previous studies can be explained by the structural difference between and adsorbed species on the δ-MnO2 phase in ferromanganese oxides. In contrast, smaller fractionation of Mo isotopes on ferrihydrite is due to little change in the Mo local structures during its adsorption to ferrihydrite.The structures of Mo species adsorbed on crystalline Fe (oxyhydr)oxides, goethite, and hematite were also investigated at pH 8 and I = 0.70 M (NaNO3). Our XAFS analyses revealed that Mo forms inner-sphere complexes on both minerals: Td edge-sharing (46%) and Oh double corner-sharing (54%) for goethite, and Td double corner-sharing (14%) and Oh edge-sharing (86%) for hematite. These structural information, combined with those for amorphous ferrihydrite and δ-MnO2, show the excellent correlation with the magnitude of adsorptive isotopic fractionation of Mo reported in previous studies: the proportion of Oh species or their magnitude of distortion in Mo surface complexes become larger in the order of ferrihydrite < goethite < hematite < δ-MnO2, a trend identical to the magnitude of isotopic fractionation.Based on the comparison with previous reports for Mo surface species on various oxides, the chemical factors that affect Mo surface complex structures were also discussed. The hydrolysis constant of cation in oxides, log KOH (or the acidity of the oxide surfaces, PZC) is well correlated with the mode of attachment (inner- or outer-sphere) of Mo surface complexes. Furthermore, the symmetric change in Mo species from Td to Oh is suggested to be driven by the formation of inner-sphere complexes on specific sites of the oxide surfaces. 相似文献
65.
Makoto Yamada Shinji Ohsawa Kohei Kazahaya Masaya Yasuhara Hiroshi Takahashi Kazuhiro Amita Hideo Mawatari Shin Yoshikawa 《Journal of Geochemical Exploration》2011
To understand deep groundwater flow systems and their interaction with CO2 emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ13CDIC) and DIC concentrations of the sampled waters show that magma-derived CO2 mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ13CDIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ18O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ13CDIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO2 is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO2 mixes into deeper groundwater flowing nearer the magma conduit or chamber. 相似文献
66.
67.
Rato M Gaspar MB Takahashi S Yano S Tanabe S Barroso C 《Marine pollution bulletin》2008,56(7):1323-1331
Imposex and organotin (OT) tissue contamination of the netted whelk Nassarius reticulatus (L.) were assessed in the continental shelves around the main estuaries of the central coast of Portugal (Lisbon: Tagus estuary; Setúbal: Sado estuary) and the main coastal lagoon in the Southern of Portugal (Faro: Ria Formosa). Pollution levels were higher in areas of more intense boat traffic and shipyard activities and imposex showed a clear decreasing gradient from the estuaries to the offshore, in relation to a similar gradient of tissue contamination by tributyltin. Remarkably, imposex was extensively spread over the adjacent continental shelves of Tagus and Sado estuaries. The current work shows that TBT pollution is undoubtedly a matter of concern not only for the above estuaries where harbours are implanted but also for the adjacent continental shelves, regardless the massive dilution of contaminants that may occur in these deeper areas. 相似文献
68.
69.
Stable carbon isotope distribution of particulate organic matter in the ocean: a model study 总被引:4,自引:0,他引:4
Matthias Hofmann Dieter A. Wolf-Gladrow Taro Takahashi Steward C. Sutherland Katharina D. Six Ernst Maier-Reimer 《Marine Chemistry》2000,72(2-4)
The stable carbon isotopic composition of particulate organic matter in the ocean, δ13CPOC, shows characteristic spatial variations with high values in low latitudes and low values in high latitudes. The lowest δ13CPOC values (−32‰ to −35‰) have been reported in the Southern Ocean, whereas in arctic and subarctic regions δ13CPOC values do not drop below −27‰. This interhemispheric asymmetry is still unexplained. Global gradients in δ13CPOC are much greater than in δ13CDIC, suggesting that variations in isotopic fractionation during organic matter production are primarily responsible for the observed range in δ13CPOC. Understanding the factors that control isotope variability is a prerequisite when applying δ13CPOC to the study of marine carbon biogeochemistry. The present model study attempts to reproduce the δ13CPOC distribution pattern in the ocean. The three-dimensional (3D) Hamburg Model of the Oceanic Carbon Cycle version 3.1 (HAMOCC3.1) was combined with two different parametrizations of the biological fractionation of stable carbon isotopes. In the first parametrization, it is assumed that the isotopic fractionation between CO2 in seawater and the organic material produced by algae, P, is a function of the ambient CO2 concentration. The two parameters of this function are derived from observations and are not based on an assumption of any specific mechanism. Thus, this parametrization is purely empirical. The second parametrization is based on fractionation models for microalgae. It is supported by several laboratory experiments. Here the fractionation, P, depends on the CO2 concentration in seawater and on the (instantaneous) growth rates, μi, of the phytoplankton. In the Atlantic Ocean, where most field data are available, both parametrizations reproduce the latitudinal variability of the mean δ13CPOC distribution. The interhemispheric asymmetry of δ13CPOC can mostly be attributed to the interhemispheric asymmetry of CO2 concentration in the water. However, the strong seasonal variations of δ13CPOC as reported by several authors, can only be explained by a growth rate-dependent fractionation, which reflects variations in the cellular carbon demand. 相似文献
70.
Shuichi Tanahashi Hiroshi Kawamura Toshihiko Matsuura Tomoyuki Takahashi Hiroyuki Yusa 《Journal of Oceanography》2000,56(3):345-358
We have developed an algorithm to estimate the wide-ranging Sea Surface Temperature (SST) data from the GMS-5 (Geostationary Meteorological Satellite) S-VISSR (Stretched-Visible Infrared Spin Scan Radiometer). Better SST estimates are realized by averaging the temporal variation of the VISSR calibration table and decreasing noise of the split-window terms using a spatial filter. The effects of the satellite zenith angle were examined in detail for better estimates, and VISSR-derived SSTs with root-mean-square (rms) error of 0.8 K were achieved using a new algorithm. The accuracy of SST estimates has been improved by using the temporal-spatial average of the split-window terms. Using the new techniques, we demonstrate that the hourly wide-ranging SST image data can be used to study the daily variations of SSTs in the Northern and Southern Pacific Oceans. 相似文献